Analyses and Applications of Metalloprotein Complexes
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چکیده
منابع مشابه
The Kinetic and Thermal Degradation Studies of N-(4-Acetyl-phenyl)-acetimidic Acid Pyridine-3-yl ester Metal(II) Complexes
Schiff base complexes of transition metals are of particular interest to inorganic chemists because of their structural, spectral and chemical properties, which are often strongly dependant on the nature of the ligand structure. Large number of metal (II) complexes with Schiff-base ligands has been extensively studied for their interesting structural specialties, applications and properties. Th...
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Zinc is one of the most important metal ions found in proteins performing specific functions associated with life processes. Coordination geometry of the zinc ion in the active site of the metalloprotein-ligand complexes poses a challenge in determining ligand binding affinities accurately in structure-based drug design. We report here an all atom force field based computational protocol for es...
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Nickel (II) and copper (II) complexes of highly unsymmetrical tetradentate Schiff base have been synthesized by the template reaction of half-units N-(1-hydroxy-2-acetonaphtone)-1-amino-2-phenyleneimine (HL) and N-(2-hydroxyacetophenone)-1-amino-2-phenyleneimine (HL1) with the glyoxalphenylhydrazone. The complexes have been characterized by elemental analyses, conductance, IR, 1H NMR and UV spe...
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In this paper, two double helical dinuclear copper(II) complexes of bis-N,O-bidentate Schiff base ligands bis(3-methoxy-N-salicylidene-4,4'-diaminodiphenyl)sulfone (L1) and bis(5-bromo-N-salicylidene-4,4'-diaminodiphenyl)sulfone (L2) were prepared and characterized by elemental analyses (CHN), as well as thermal analysis. Elemental analyses (CHN) suggested that the reaction between ligands and ...
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New hetero-binuclear Hg-Cu Schiff base complexes were prepared by reaction of 2,2'-[1,1'-(2,2-dimethylpropane-1,3-diyldinitrilo)-diethyldyne]diphenolato}copper(II) (CuL1) and 6,6'-X-2,2'-[(2,2-dimethylpropane-1,3-diyl)bis(nitrilomethanylylidene)]diphenolato copper(II) [(X = ethoxy (CuL2) and methoxy (CuL3)], with HgCl2 to give [Cu(L1)HgCl2] (1), [Cu(L2)HgCl2] (2), and [Cu(L3)HgCl2] (3), res...
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